Mark Selby will begin the defence of his Masters title against Mark King at Wembley Arena next January.
Ronnie O'Sullivan, Selby's beaten opponent in last season's final, will face Mark Allen, who beat him in the second round of the 2009 World Championship.
Reigning world champion Neil Robertson tackles six times Masters champion Stephen Hendry while Jamie Cope makes his Wembley debut against Shaun Murphy.
The format includes scope for two wildcards but this is still to be confirmed.
Mark Selby v Mark King
Shaun Murphy v Jamie Cope
Mark Williams v Ding Junhui
John Higgins v Graeme Dott
Ali Carter v Peter Ebdon
Stephen Maguire v Marco Fu
Ronnie O'Sullivan v Mark Allen
Neil Robertson v Stephen Hendry